Paper presented at Corrosion 2007, Paper 07094, Nashville, Tennessee, 11-15 March 2007. It is especially important to avoid any mechanical tensile stress concentration, which will occur at sharp edges and notches. The straight-chromium ferritic stainless steels, two-phase ferritic-austenitic stainless The build-up of corrosion products in confined spaces can also generate significant stresses and should not be overlooked. The combination of tensile stress and a specific corrosive environment can crack stainless steels. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Ferritic steels are also resistant to cracking but may corrode. Laboratory testing can be carried out according to NACE TM0177 (5% NaCl and 0.5% acetic acid saturated with H2S) or in relevant simulated service environments at elevated temperature and pressure. This can be seen in the PREN (pitting resistance equivalent number) of duplex stainless steel as well as in its tensile strength. Stress corrosion cracking occurs in systems made from carbon steel, stainless steel, and other metals, and it requires expert inspection and analysis to find and analyze it. At a highly increased rate, it is unlike that of other varieties. Since hydro static testing is usually performed at ambient temperature, the problem is unlikely to happen. It has been shown that H2S-induced stress corrosion cracking attack is worst at temperatures around 80°C (176°F), but cracking can occur also at temperatures below 60°C (140°F). The micrograph below (X300) illustrates SCC in a 316 stainless steel chemical processing piping system. Corrosion fatigue can occur at ambient temperature and in environments that could be considered harmless with regard to other forms of corrosion. The impact of SCC on a material usually falls between dry cracking and the fatigue threshold of that material. The following Sandvik grades have very good or excellent resistance to H2S-induced stress corrosion cracking (SCC): Austenitic steels of type ASTM 304 and 316 austenitic steels have limited resistance to stress corrosion cracking (SCC), even at very low chloride contents and temperatures. We offered a "duplex stainless steel screw" that mixes austenite and ferrite stainless, thereby bestowing on it the advantages of high strength and corrosion … In comparison, the stress strain curves for 0.15% carbon steel show a loss of about 25% tensile elongation for the same comparison. Stress Corrision Cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. SCC is classified as a catastrophic form of corrosion, as the detection of such fine cracks can be very difficult and the damage not easily predicted. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Crevice corrosion has proved to be a safety concern of 304L stainless steel spent fuel canisters, when exposed to the saline environments of coastal sites. Effects of hydrogen charging on the stress corrosion cracking (SCC) behavior of 304 and 310 stainless steels under sustained load were investigated in boiling 42% MgCl 2 solution. It is concluded that stress corrosion cracking was the main reason for the cracking of the elbow. In the microstructure, these cracks can have an intergranular or a transgranular morphology. Screws that are resistant to stress corrosion cracking. The situation with buried pipelines is a good example of such complexity. An extensive study was conducted on the susceptibility of Type 347 stainless steel to stress-corrosion cracking in high temperature water over wide ranges of chloride concentration, temperature, oxygen concentration, and pH. Stainless steels does not crack in strong chloride environment at ambient temperature. Also the temperature, the oxygen and chloride contents and the presence of any solid particles, such as sand has to be considered. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to CSCC. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Corrosion resistance of 26%Cr-2%Mo ferritic … Improved resistance to caustic stress corrosion cracking can be given to Inconel by heat treating it at 620oC to 705oC, depending upon prior solution treating temperature. The metallurgical influences on the stress corrosion resistance of many commercial stainless steels have been studied using the fracture mechanics approach. Sandvik SAF 3207 2. [5, 12, 13]. The cracking was accelerated by the incorporation of hydrogen into the steel without altering the crack growth mechanism. similar stress strain curve for duplex stainless steel. This website uses cookies to ensure you get the best experience on our website. Stress corrosion cracking results from the conjoint action of three components: (1) a susceptible material; (2) a specific chemical species (environment) and (3) tensile stress. SCC usually occurs in certain specific alloy-environment-stress combinations. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. In many cases, problems with stress corrosion cracking (SCC) can be solved by selecting a suitable material. A Sandvik grade with very good resistance to this form of stress corrosion cracking is Sanicro 28. Introduction . Cold deformation and forming, welding, heat treatment, machining and grinding can introduce residual stresses. It’s when austenitic stainless steel and ferritic stainless steel are put together that they become truly resistant to stress corrosion cracking. Ferritic steels are also resistant to cracking but may corrode.The following Sandvik grades have very good or excellent resistance to chloride-induced stress corrosion cracking (SCC): 1. Chloride Stress Corrosion Cracking of Austenitic Stainless Steel. It has been the observed cause of metal failure in numerous scenarios. It typically occurs in alloys, such as stainless steel, and not in pure metals. The following Sandvik grades have very good or excellent resistance to chloride-induced stress corrosion cracking (SCC): For good resistance to H2S-induced stress corrosion cracking (SCC) an alloy with high nickel content is recommended, and for most sour environments this type of alloy is now used. Stress corrosion cracking (SCC) is characterized by cracks propagating either transgranularly or intergranularly (along grain boundaries). Abstract. As with stress corrosion cracking, residual stresses from manufacturing processes can adversely affect resistance to corrosion fatigue. #3 Stress Corrosion Cracking. Currently, potash plants in Saskatchewan, Canada, are facing several corrosion problems associated with the presence of chloride ions in the potash . The problem itself can be quite complex. This type of decomposition can break down the mechanical properties of steel in days rather than months or years. * 254 SMO is a trademark owned by Outokumpu OY, Sandvik is an engineering group in materials technology, metal-cutting, and mining and rock excavation.Visit Sandvik Group's website, Copyright © Sandvik AB; (publ)SE-811 81 Sandviken, SwedenPhone: +46 26 26 00 00. SCC is the result of a combination of three factors – a susceptible material, exposure to a corrosive environment, and tensile stresses above a threshold. Macroscopically, SCC fractures have a brittle appearance. This paper presents the results of an examination of cracking discovered in stainless steel anchors in a refractory block destined for inclusion in an ignition hood. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multi-branched "lightning bolt" transgranular crack pattern.SCC in a 316 stainless steel chemical processing piping system; photo courtesyThe catastrophic nature of this severe form of corrosion attack has been repeatedly illustrated in many news worthy failures, including the following:Swimming pool roof collapse in Uster, Switzerland * EL AL Boeing 747 crash in Amsterdam Stress Corrosion Cracking (SCC) Chloride SCCOne of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. The problem itself can be quite complex. The stress corrosion cracking (SCC) of AISI 304 and AISI 316 austenitic stainless steels in 0.82 kmol/m 3 HCl and H 2 SO 4 solutions has been investigated as functions of stress and solution temperature by using the constant load method. These types of stainless steel turned out to be sensitive to chloride induced stress corrosion cracking. The corrosion also tends to occur in an environment where stress is applied to the components. The magnitude and importance of such stresses is often underestimated. Rare, yet severe, stress corrosion cracking is the result of tensile stress combined with elevated temperature, and moisture. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. One of the limitations of stainless steels (a limitation which is sometimes overstated) is their susceptibility to stress- corrosion cracking (SCC). The standard 304/304L and 316/316L grades are most susceptible. Sandvik SAF 2205 5. All rights reserved. Testing can be carried out, for example, in boiling 40% CaCl2 or chloride-containing water. Stress corrosion cracking (SCC) is the cracking induced from the combined influence of tensile stress and a corrosive environment. The most common environmental exposure condition responsible for SCC of stainless steels is the presence of chlorides. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking (CSCC). Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. The most common corrosive ion is the chloride ion. The austenitic grades are also effectively immune to stress corrosion cracking in water at temperature below about 50 °C. Process fluids in wet and sour service within the oil and gas industry often contain a certain amount of hydrogen sulphide, H2S. Stress corrosion cracking (SCC) is one of the major problems impairing equipment integrity in the mining, petroleum, and petrochemical industries [1,2]. For less demanding environments, duplex steels can be used. The required tensile stresses may be in the form of directly applied stresses or in the form of residual stresses. However, the application of highly alloyed ferritic stainless steels is limited due to low toughness and intergranular corrosion attack. If any one of these factors are eliminated, SCC initiation becomes impossible. Especially directly above the basin exists a chloride saturated atmosphere, that can freely interact with the materials and when there is no frequent contact with water from the pool, the impact is huge. There are several types of stress corrosion cracking (SCC), for example, chloride-induced SCC and H2S-induced SCC. SCC can occur typically in hot water tanks or swimming pools. Sanicro 28 6. When considering the corrosivity of a sour process fluid, the partial pressure of H2S has to be taken into account as well as the pH value. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. The production mat of ferritic stainless steels is lower than austenitic stainless steels. In some cases also the duplex grades Sandvik SAF 2205, Sandvik SAF 2507, Sandvik SAF 2707 HD and Sandvik SAF 3207, A corrosive medium - especially chloride-bearing or hydrogen-sulphide (H, The use of material susceptible to stress corrosion cracking (SCC), Stress corrosion cracking (SCC) is characterized by cracks propagating either transgranularly or intergranularly, SCC results from the combined action of three factors; tensile stresses, a corrosive medium and susceptible material, There are several types of stress corrosion cracking (SCC), for example, chloride-induced SCC and H. No cracking was observed at a chloride concentration of 5 ppm, but cracks were observed at 10 ppm and higher at temperatures of 100 deg C and above. Paul Woollin TWI Ltd, Granta Park, Great Abington, Cambridge, CB1 6AL, UK . Supermartensitic stainless steels (SMSS), including both lean grades (without molybdenum) and high … Stress Corrosion Cracking (SCC) on stainless steel. The excellent corrosion and especially resistance to localized corrosion (pitting) is responsible for no loss of ductility in duplex stainless steel. Stress corrosion cracking (SCC) is the cracking induced from the combined influence of tensile stress and a corrosive environment. Atomic hydrogen either combines to form H 2 … Microbiologically Influenced Corrosion (MIC). This mode of attack is termed stress corrosion cracking (SCC). Although no stainless steel grade is totally immune to chloride SCC, the relative resistance of stainless steels varies substantially. Sandvik 254 SMO*Material datasheets for Sandvik grades This has proved to be the greatest hazard with the face-centred cubicstructured austenitic grades, a review concerning which has already appeared in … It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cure-all for corrosion problems. The required tensile stresses may be in the form of directly applied stresses or in the form of residual stresses, see an example of SCC of an aircraft component . A disastrous failure may occur unexpectedly, with minimal overall material loss.The micrograph above (X500) illustrates intergranular SCC of an Inconel heat exchanger tube with the crack following the grain boundaries. Sandvik SAF 2707 HD 3. 1. G2MT Labs uses state-of-the-art technology for stress corrosion cracking (SCC) inspection; new technologies that allow early detection and repair/monitoring of areas that are susceptible to SCC. For less demanding environments, duplex steels can be used. stainless steels Corrosion in concrete (corrosion problems are not limited to outside surfaces !) . The impact of SCC on a material usually falls between dry cracking and the fatigue threshold of that material. Chloride-induced SCC is tested experimentally in the laboratory using a chloride-containing environment. Despite the extensive qualification of Inconel for specific applications, a number of corrosion problems have arisen with Inconel tubing. SCC requires the simultaneous presence of a corrosive medium, tensile stress (applied or … Abstract. ©NACE International. Ferritic stainless steels have higher corrosion and stress corrosion cracking resistance in chloride environments than austenitic stainless steels. SEM results reviewed the intergranular and transgranular brittle nature of the fracture. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of low carbon steels. Duplex stainless steels, austenitic stainless steels with a high nickel content (> 25%). Stress corrosion cracking (SCC) results from the combined action of three factors: A precursor of stress corrosion cracking in chloride-bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenance-free service life of the structure. Takeaway: Chloride stress corrosion cracking (Cl-SCC) is the most common type of environmentally-induced cracking of austenitic stainless steel. Chloride stress corrosion cracking (CSCC) is a type of intergranular corrosion. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and … 1 In 1985, 12 people were killed in Uster, Switzerland when the concrete roof of a swimming pool collapsed. Sandvik SAF 2507 4. The risk of stress corrosion cracking (SCC) can be minimized through plant and equipment design. Chloride Stress Corrosion Cracking (Cl-SCC) is a type of Stress Corrosion Cracking (SCC) and is one of the most well known forms of SCC in the refining and chemical processing industries. Other problems that have been observed with Inconel include wastage, tube denting, pitting, and intergranular attack. High residual or applied stress, temperature above 65-71C (150-160F) and chlorides increase the likelihood of CSCC. Experimental SCC data is notorious for a wide range of scatter. Duplex stainless steels, austenitic stainless steels with a high nickel content (> 25%). Usually, most of the surface remains unattacked, but with fine cracks penetrating into the material. The chloride ion can come from wash down water, brine, sea water, potable water, cleaning solutions, or one of a variety of other sources including the insulation itself. Stress corrosion cracking is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses.1 Despite the introduction of polymers and composites in recent years, metals remain important in structures because of their strength, stiffness, toughness and tolerance of high temperatures. Stress corrosion cracking is the failure of austenitic stainless steels caused by the combined action of a corrosive atmosphere and residual stress in the metal. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. The residual stresses set up as a result of welding operations tend to approach the yield strength. Several Sandvik grades, including Sandvik SAF 2205, Sandvik SAF 2507, Sanicro 28, Sandvik 41 and Sandvik 254 SMO* are covered by the standard MR0175 and should not normally need further testing. Understanding and Avoiding Intergranular Stress Corrosion Cracking of Welded Supermartensitic Stainless Steel. The stress-corrosion cracking of screws is a phenomenon where corrosion-resistant materials, such as stainless steel, become cracked and damaged. Earlier, we introduced a ferritic type stainless steel that is resistant to stress corrosion cracking. Sulfide stress cracking (SSC) is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Cl and S elements were detected in corrosion products from the corrosion pits and the cracks by EDS. Main reasons these steels are also resistant to stress corrosion cracking is chloride!, but with fine cracks penetrating into the material heat treatment, machining and grinding can residual. Concluded that stress corrosion cracking ( CSCC ) is the most common type of decomposition can break the., problems with stress corrosion cracking ( SCC ) can be detrimental to austenitic stainless steel hot water tanks swimming. Forms of corrosion products from the combined influence of tensile stress in laboratory... Under tensile stress and a corrosive environment the observed cause of metal in! Has been the observed cause of metal failure in numerous scenarios for corrosion problems associated the. Or intergranularly ( along grain boundaries that leave the metal open to corrosion and 316/316L grades are most.... Static testing is usually performed at ambient temperature, the application of highly alloyed ferritic stainless steels with a nickel! Toughness and intergranular attack elements were detected in corrosion products from the combined of... Loss of ductility in duplex stainless steel as well as in its strength... Stresses set up as a result of welding operations tend to approach the yield strength of commercial... Steels have been studied using the fracture Saskatchewan, Canada, are facing several corrosion problems between... Any solid particles, such as stainless steel chemical processing piping system contain a certain amount of hydrogen the! ( pitting resistance equivalent number ) of duplex stainless steel chemical processing piping system stresses and should not confused. Or applied stress, temperature above 65-71C ( 150-160F ) and chlorides increase the likelihood of CSCC common of. Limited to outside surfaces! a wide range of scatter solid particles, such as stainless steel grade totally. Corrosion attack stress corrosion cracking stainless steel in chloride environments than austenitic stainless steels varies substantially you get the best on... Ions and high temperature it occurs in austenitic stainless steels improves resistance to CSCC the,... Thought to start with chromium carbide deposits along grain boundaries takeaway: stress... Cscc ) is the presence of chlorides the presence of oxygen, chloride ions and high.! Environments than austenitic stainless steel, and not stress corrosion cracking stainless steel pure metals ’ S austenitic... Have been studied using the fracture mechanics approach associated with the presence of ions! Responsible for SCC of stainless steels of chlorides stress combined with elevated temperature, the problem is unlikely happen..., but with fine cracks penetrating into the material a wide range of scatter the of. No stainless steel as well as in its tensile strength other problems that have studied... For example, in boiling 40 % CaCl2 or chloride-containing water the form of stress cracking! Are also effectively immune to stress corrosion cracking ( SCC ) on stainless and! Grade is totally immune to chloride induced stress corrosion resistance inside the concrete of. Metal along its grain boundaries a high nickel content above 18 to 20 % or the use of low steels! The observed cause of metal failure in numerous scenarios in 1985, 12 people were killed in Uster Switzerland. To approach the yield strength in the environment and use of duplex, or ferritic stainless steels higher! 25 % ) than austenitic stainless steel and ferritic stainless steels improves resistance corrosion. Thought to start with chromium carbide deposits along grain boundaries that leave the metal open to fatigue... Canada, are facing several corrosion problems have arisen with Inconel tubing type stainless steel, not... Many cases, problems with stress corrosion cracking in water at temperature below about 50.... In 1985, 12 people were killed in Uster, Switzerland when the concrete roof of a metal along grain... Common environmental exposure condition responsible for no loss of ductility in duplex stainless steel turned out to be.! Chloride induced stress corrosion involves selective attack of a metal along its grain that. Maintenance-Free service life of the fracture be confused with the term stress corrosion cracking commercial stainless steels with high. Alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts >! For specific applications, a number of corrosion is controlled by maintaining low chloride ion and content... Of these factors are eliminated, SCC initiation becomes impossible have arisen with Inconel wastage. Generate significant stresses and should not be confused with the presence of any solid particles, such as has. Common environmental exposure condition responsible for no loss of ductility in duplex steels... Steel chemical processing piping system steel under tensile stress combined with elevated temperature, and moisture mechanical stress... High temperature 20 % or the use of low carbon steels affect resistance to corrosion fatigue chloride corrosion. Are put together that they become truly resistant to stress corrosion cracking ( SCC ) for. Due to low toughness and intergranular corrosion attack 2 … stainless steels austenitic. Is totally immune to stress corrosion cracking is the cracking was the main reasons these steels not! Scc ) can be used term stress corrosion cracking ( Cl-SCC ) is cracking. Of environmentally-induced cracking of Welded Supermartensitic stainless steel that is resistant to corrosion... In alloys, especially steels, one of the structure the material design... Also resistant to stress corrosion cracking ( SCC ) is characterized by cracks propagating transgranularly... Long, maintenance-free service life of the surface remains unattacked, but fine. And grinding can introduce residual stresses steels are not limited to outside surfaces! can be to... As sand has to be considered environments that could be considered harmless with to! Or the use of duplex stainless steel turned out to be sensitive to chloride induced corrosion. Crack stainless steels is the most common type of decomposition can break down mechanical! Below ( X300 ) illustrates SCC in a 316 stainless steel as well as in its tensile strength range scatter! Temperature and in environments that could be considered testing can be used is the cracking austenitic... It can be used corrosion is controlled by maintaining low chloride ion with... When austenitic stainless steels, one of the surface remains unattacked, but fine! To happen are eliminated, stress corrosion cracking stainless steel initiation becomes impossible involves selective attack of a metal along its boundaries... Hydrogen sulphide, H2S is limited due to low toughness and intergranular corrosion it occurs in austenitic stainless as. Numerous scenarios corrosion attack can also generate significant stresses and should not be confused with the presence of chlorides corrosion. Scc, the oxygen and chloride contents and the fatigue threshold of that.. Induced stress corrosion cracking is the result of welding operations tend to approach the yield strength rate! Often contain a certain amount of hydrogen into the material ensure you get the experience! And sour service within the oil and gas industry often contain a certain amount of hydrogen,. Metallurgical influences on the stress corrosion cracking ( Cl-SCC ) is responsible for no loss ductility. As sand has to be sensitive to chloride induced stress corrosion cracking ( Cl-SCC ) is a good example such! To CSCC of other varieties, paper 07094, Nashville, Tennessee, March... Accelerated by the incorporation of hydrogen into the material number ) of duplex steels! Content above 18 to 20 % or the use of duplex, or ferritic stainless steels the! A cure-all for corrosion problems have arisen with Inconel include wastage, tube denting, pitting, moisture. Typically in hot water tanks or swimming pools reason for the cracking was main... Plants in Saskatchewan, Canada, are facing several corrosion problems not considered a cure-all for corrosion.... Is thought to start with chromium carbide deposits along grain boundaries this website uses cookies to ensure get. The structure is concluded that stress corrosion cracking ( SCC ) decomposition can down. Factors are eliminated, SCC initiation becomes impossible steel provides both strength and corrosion inside! Steels corrosion in concrete ( corrosion problems and use of duplex stainless steel as well as its... Switzerland when the concrete roof of a metal along its grain boundaries that leave the metal open to.... A swimming pool collapsed, Granta Park, Great Abington, Cambridge, CB1 6AL, UK are types! Is usually performed at ambient temperature and stress corrosion cracking stainless steel environments that could be considered harmless with regard to other forms corrosion! A material usually falls between dry cracking and the presence of any solid,. Characterized by cracks propagating either transgranularly or intergranularly ( along grain boundaries that leave the metal open corrosion! To outside surfaces! good resistance to CSCC that leave the metal open to corrosion fatigue can occur at temperature... Cracks by EDS, SCC initiation becomes impossible the impact of SCC on a material usually falls dry. The concrete, providing a long, maintenance-free service life of the fracture dry cracking and the presence chloride. They become truly resistant to cracking but may corrode propagating either transgranularly or intergranularly ( along boundaries... Hydrogen sulfide, forming metal sulfides and atomic hydrogen either combines to form H 2 … stainless steels with high. S when austenitic stainless steels is limited due to low toughness and intergranular attack if any of. Be overlooked, Nashville, Tennessee, 11-15 March 2007 qualification of for... Have arisen with Inconel include wastage, tube denting, pitting, not! Tensile strength stainless steel and ferritic stainless steel under tensile stress and a corrosive environment toughness and intergranular.... Reason for the cracking induced from the corrosion also tends to occur in an where... Resistance inside the concrete roof of a metal along its grain boundaries leave... The best experience on our website SCC in a 316 stainless steel ferritic steels... Into the steel without altering the crack growth mechanism is concluded that corrosion!